Actinium
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| General | ||||||||||||||||||||||||||||||||||
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| Name, Symbol, Number | actinium, Ac, 89 | |||||||||||||||||||||||||||||||||
| Chemical series | actinides | |||||||||||||||||||||||||||||||||
| Group, Period, Block | 3, 7, f | |||||||||||||||||||||||||||||||||
| Appearance | silvery | |||||||||||||||||||||||||||||||||
| Standard atomic weight | (227) g·mol−1 | |||||||||||||||||||||||||||||||||
| Electron configuration | [Rn] 6d1 7s2 | |||||||||||||||||||||||||||||||||
| Electrons per shell | 2, 8, 18, 32, 18, 9, 2 | |||||||||||||||||||||||||||||||||
| Physical properties | ||||||||||||||||||||||||||||||||||
| Phase | solid | |||||||||||||||||||||||||||||||||
| Density (near r.t.) | 10 g·cm−3 | |||||||||||||||||||||||||||||||||
| Melting point | (circa) 1323 K (1050 °C, 1922 °F) | |||||||||||||||||||||||||||||||||
| Boiling point | 3471 K (3198 °C, 5788 °F) | |||||||||||||||||||||||||||||||||
| Heat of fusion | 14 kJ·mol−1 | |||||||||||||||||||||||||||||||||
| Heat of vaporization | 400 kJ·mol−1 | |||||||||||||||||||||||||||||||||
| Heat capacity | (25 °C) 27.2 J·mol−1·K−1 | |||||||||||||||||||||||||||||||||
| Atomic properties | ||||||||||||||||||||||||||||||||||
| Crystal structure | cubic face centered | |||||||||||||||||||||||||||||||||
| Oxidation states | 3 (neutral oxide) | |||||||||||||||||||||||||||||||||
| Electronegativity | 1.1 (scale Pauling) | |||||||||||||||||||||||||||||||||
| Ionization energies | 1st: 499 kJ/mol | |||||||||||||||||||||||||||||||||
| 2nd: 1170 kJ/mol | ||||||||||||||||||||||||||||||||||
| Atomic radius | 195 pm | |||||||||||||||||||||||||||||||||
| Miscellaneous | ||||||||||||||||||||||||||||||||||
| Magnetic ordering | no data | |||||||||||||||||||||||||||||||||
| Thermal conductivity | (300 K) 12 W·m−1·K−1 | |||||||||||||||||||||||||||||||||
| CAS registry number | 7440-34-8 | |||||||||||||||||||||||||||||||||
| Selected isotopes | ||||||||||||||||||||||||||||||||||
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Actinium (IPA: /akˈtɪniəm/) is a chemical element in the periodic table that has the symbol Ac and atomic number 89.
Contents
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[edit] Notable characteristics
Actinium is a silvery, radioactive, metallic element. Due to its intense radioactivity, Actinium glows in the dark with a pale blue light. It is found only in traces in uranium ores as 227Ac, an α and β emitter with a half-life of 21.773 years. One ton of uranium ore contains about a tenth of a gram of actinium.
[edit] Applications
It is about 150 times as radioactive as radium, making it valuable as a neutron source. Otherwise it has no significant industrial applications.
225Ac is used in medicine to produce 213Bi in a reusable generator or can be used alone as an agent for radio-immunotherapy for Targeted Alpha Therapy (TAT). 225Ac was first produced artificially by the ITU in Germany using a cyclotron and by Dr Graeme Melville at St George Hospital in Sydney using a linac in 2000.
[edit] History
Actinium was discovered in 1899 by André-Louis Debierne, a French chemist, who separated it from pitchblende. Friedrich Oskar Giesel independently discovered actinium in 1902 and called it "emanium" in 1904. Debierne's name was retained because it had seniority. The chemical behavior of actinium is similar to that of the rare earth lanthanum.
The word actinium comes from the Greek aktis, aktinos, meaning beam or ray.
[edit] Occurrence
Actinium is found in trace amounts in uranium ore, but more commonly is made in milligram amounts by the neutron irradiation of 226Ra in a nuclear reactor. Actinium metal has been prepared by the reduction of actinium fluoride with lithium vapor at about 1100 to 1300ºC.
[edit] Isotopes
Naturally occurring actinium is composed of 1 radioactive isotope; 227Ac. 36 radioisotopes have been characterized with the most stable being 227Ac with a half-life of 21.772 y, 225Ac with a half-life of 10.0 days, and 226Ac with a half-life of 29.37 h. All of the remaining radioactive isotopes have half-lifes that are less than 10 hours and the majority of these have half lifes that are less than 1 minute. The shortest-lived isotope of actinium is 217Ac which decays through alpha decay and electron capture. It has a half-life of 69 ns. Actinium also has 2 meta states.
Purified 227Ac comes into equilibrium with its decay products at the end of 185 days, and then decays according to its 21.773-year half-life.
The isotopes of actinium range in atomic weight from 206 u (206Ac) to 236 u (236Ac).
[edit] Precautions
227Ac is extremely radioactive, and in terms of its potential for radiation induced health effects, 227Ac is even more dangerous than plutonium. Ingesting even small amounts of 227Ac would kill that person.